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241.
Healey A.J. Rock S.M. Cody S. Miles D. Brown J.P. 《Oceanic Engineering, IEEE Journal of》1995,20(4):354-361
This paper proposes a novel approach to modeling the four quadrant dynamic response of thrusters as used for the motion control of ROV and AUV underwater vehicles. The significance is that these vehicles are small in size and respond quickly to commands. Precision in motion control will require further understanding of thruster performance than is currently available. The model includes a four quadrant mapping of the propeller blades lift and drag forces and is coupled with motor and fluid system dynamics. A series of experiments is described for both long and short period triangular, as well as square wave inputs. The model is compared favorably with experimental data for a variety of differing conditions and predicts that force overshoots are observed under conditions of rapid command changes. Use of the model will improve the control of dynamic thrust on these vehicles 相似文献
242.
We have conducted the first systematic analyses of molecular distribution and δD values of individual compounds in pyrolysates of insoluble organic matter (IOM) from different carbonaceous chondrite groups, using flash pyrolysis coupled to gas chromatography-mass spectrometry and compound-specific D/H analysis. IOM samples from six meteorites of different classifications, Elephant Moraine (EET) 92042 (CR2), Orgueil (CI1), Allan Hills (ALH) 83100 (CM1/2), Murchison (CM2), ALH 85013 (CM2), and Tagish Lake (C2) were isolated and studied. Except for the pyrolysate of Tagish Lake IOM, pyrolysates of all five meteorite IOM samples were dominated by an extensive series of aromatic (C1 to C7 alkyl-substituted benzenes, C0 to C2 alkyl-substituted naphthalenes), with aliphatic (straight chain and branched C10 to C15 alkanes) hydrocarbons and several S- and O- containing compounds (C1 to C2 alkylthiophenes, benzothiophene, benzaldehyde) being also present. The strong similarity in the pyrolysates of different carbonaceous chondrites suggests certain common characteristics in the formation mechanisms of IOM from different meteorites. The Tagish Lake IOM sample is unique in that its pyrolysate lacks most of the alkyl-substituted aromatic hydrocarbons detected in other meteorite IOM samples, suggesting distinctively different formation processes. Both bulk δD values of meteorite IOMs and weighted-average δD values of individual compounds in pyrolysates show a decreasing trend: CR2 > CI1 > CM2 > C2 (Tagish Lake), with the EET 92042 (CR2) IOM having the highest δD values (∼2000‰ higher than other samples). We attribute the high D contents in the IOM to primitive interstellar organic sources. 相似文献
243.
Paul R. Haberstroh Jay A. Brandes Angela F. Dickens George Cody 《Geochimica et cosmochimica acta》2006,70(6):1483-1494
The chemical composition of the graphitic black carbon (GBC) fraction of marine organic matter was explored in several marine and freshwater sedimentary environments along the west coast of North America and the Pacific Ocean. Analysis by carbon X-ray absorption near-edge structure spectroscopy and scanning transmission X-ray microscopy shows the GBC fraction of Stillaguamish River surface sediments to be dominated by more highly ordered and impure forms of graphite, together forming about 80% of the GBC, with a smaller percent of an aliphatic carbon component. Eel River Margin surface sediments had very little highly ordered graphite, and were instead dominated by amorphous carbon and to a lesser extent, impure graphite. However, the GBC of surface sediments from the Washington State Slope and the Mexico Margin was composed almost solely of amorphous carbon. Pre-anthropogenic, highly oxidized deep-sea sediments from the open Equatorial Pacific Ocean contained over half their GBC in different forms of graphite as well as highly aliphatic carbon, low aromatic/highly acidic aliphatic carbon, low aromatic/highly aliphatic carbon, and amorphous forms of carbon. Our results clearly show the impact of graphite and amorphous C phases in the BC fraction in modern riverine sediments and nearby marine shelf deposits. The pre-anthropogenic Equatorial Pacific GBC fraction is remarkable in the existence of highly ordered graphite. 相似文献
244.
Mathieu Roskosz Bjorn O. Mysen George D. Cody 《Geochimica et cosmochimica acta》2006,70(11):2902-2918
Solubility and speciation of nitrogen in silicate melts have been investigated between 1400 and 1700 °C and at pressures ranging from 10 to 30 kbar for six different binary alkali and alkaline-earth silicate liquids and a Ca-Mg-alumino silicate. Experiments were performed in a piston-cylinder apparatus. The nitrogen source is silver azide, which breaks down to Ag and molecular N2 below 300 °C. At high pressure and temperature, the nitrogen content may be as high as 0.7 wt% depending on the melt composition, pressure, and temperature. It increases with T, P and the polymerization state of the liquid. Characterization by Raman spectroscopy and 15N solid state MAS NMR indicates that nitrogen is not only physically dissolved as N2 within the melt structure like noble gases, but a fraction of nitrogen interacts strongly with the silicate network. The most likely nitrogen-bearing species that can account for Raman and NMR results is nitrosyl group. Solubility data follow an apparent Henry’s law behavior and are in good agreement with previous studies when the nitrosyl content is low. On the other hand, a significant departure from a Henry’s law behavior is observed for highly depolymerized melts, which contain more nitrosyl than polymerized melts. Possible solubility mechanisms are also discussed. Finally, a multi-variant empirical relation is given to predict the relative content of nitrosyl and molecular nitrogen as a function of P, T, and melt composition and structure. This complex speciation of nitrogen in melts under high pressure may have significant implication concerning crystal-melt partitioning of nitrogen as well as for potential elemental and isotopic fractionation of nitrogen in the deep Earth. 相似文献
245.
Matrix formulation of co-kriging 总被引:11,自引:0,他引:11
Donald E. Myers 《Mathematical Geology》1982,14(3):249-257
The matrix form of the general co-kriging problem is presented. Matrix solutions are given for SRFs with covariance functions, for IRFs of order zero using variograms and for universal co-kriging. General methods for obtaining cross-covariance or cross-variogram models are given. The relationship of the general co-kriging problem to the problem of one under sampled variable is presented. 相似文献
246.
The Edgecumbe volcanic field is a Holocene volcanic province located on Kruzof Island, SE Alaska. Exposed within the 260 km2 field are basalt, andesitic basalt, andesite, dacite and rhyodacite. The rhyodacites were erupted after the basalts and before
the andesites. The volcanics, which are Al-rich (14–18 wt%) and lack an iron enrichment trend, range from tholeiites (47 wt%
SiO2) through rhyodacites (72%), but a compositional gap of approximately 9 wt% separates the dacites and rhyodacites. Initial
87Sr/86Sr ranges from 0.70297 in the basalts to 0.70440 in a pyroxene andesite. δ
18O increases across the suite: 5.8‰ to 7.9‰. Plagioclase (An32–86) is the dominant phenocryst in all but one lava. Olivine (Fo58–86) occurs in the basic lavas (<53 wt% SiO2), but is replaced by orthopyroxene (En43–73) and clinopyroxene (En31Wo41-En48Wo40) in the more siliceous volcanics. In the basalts and rhyodacites, plagioclase is weakly zoned, but extreme zoning (<30 mole%
An) is characteristic of phenocrysts in the intermediate lavas. Fractionation of the observed phenocryst assemblages could
not have produced the more silicous volcanics. Instead they were generated by partial melting of intrusive basement (87Sr/86Sr=0.70487; δ
18O: 8.7–9.3) by basaltic magma and subsequent assimilation. Mass balance calculations show the rhyodacites are almost pure
partial melt (<5% basaltic component) whereas the intermediate lavas contain between 30 and 60% partial melt. 相似文献
247.
Cody Schultz Brendan A. Anzures Ralph E. Milliken Taki Hiroi Kevin Robertson 《Meteoritics & planetary science》2023,58(2):170-194
H2O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body. 相似文献
248.
Shabnam JafariKhasragh Jennifer V. Lukovich Xianmin Hu Paul G. Myers Kevin Sydor David G. Barber 《大气与海洋》2013,51(2):120-133
ABSTRACTSea surface temperature (SST) from four Nucleus for European Modelling of the Ocean (NEMO) model simulations is analyzed to study the bulk flux parameterization to compute SST over the Hudson Bay Complex (HBC) for the summer months (August and September) from 2002 to 2009. The NEMO simulation was forced with two atmospheric forcing sets with different resolutions: the Coordinated Ocean-ice Reference Experiment, version 2 (COREv2), as the lower resolution and the Canadian Meteorological Centre’s Global Deterministic Prediction System Reforecasts (CGRF) as the higher resolution. The CGRF forcing is also implemented in the third and fourth runs using different runoff data and different NEMO resolutions (1/12° versus 1/4°). Results show that all four modelled SSTs followed observed SST patterns, with regional differences in SST bias between simulations with different atmospheric forcing. The SST differences are small between simulations forced with the same atmospheric forcing but with different model resolution or runoff. This implies that the model resolution and runoff have a small effect on the simulated SST in the HBC. Moreover, to better capture the effect of near-surface temperature (Tair) on simulated SST, we conducted three analyses using the Haney flux linearization formula. Results from these assessments did not indicate any direct influence on the model-simulated SSTs by Tair. Looking at the heat flux as a signature for SST showed that both averaged spatial distribution and time series of net heat flux produced by the three CGRF forcing simulations were higher than the net heat flux generated by the CORE 2 simulation. This was generally true for all four components of the total heat flux (sensible, latent, shortwave, and longwave) individually as well. Total heat flux in summer is governed by the shortwave heat flux, with values up to 120?W?m?2 in August, and the longwave heat flux is the main contributor to the total heat flux differences. These heat flux differences lead to corresponding colder model SSTs for the CGRF runs and warmer SSTs for the CORE 2 simulations. 相似文献
249.
English sole (Pleuronectes vetulus) and starry flounder (Platichthys stellatus) are two sympatric flatfish species which show markedly different responses to chemical contaminant exposure. Whereas English sole develop hepatic neoplasms, the prevalences of which are strongly linked to exposure to polycyclic aromatic hydrocarbons (PAHs), evidence of neoplasia is virtually nonexistent in starry flounder, even those residing in areas with very high levels of PAH in the sediments. Because PAHs are activated to genotoxic forms by the action of cytochrome P450 1A (CYP1A) in teleosts, we are examining the hypothesis that variation in the hepatic expression of this major inducible cytochrome P450 isozyme may contribute to the differential contaminant response. These two species were captured in the Duwamish Waterway, a contaminated area of Puget Sound, Washington. Catalytic activity of CYP1A [determined as aryl hydrocarbon hydroxylase (AHH) activity] was measured in the liver to quantitatively assess the relative induction of CYP1A in these two species, and AHH activity was significantly higher in English sole than in starry flounder (p = 0.015). Cellular expression of CYP1A was determined by immunohistochemical localization of tissues, using an avidin-biotin peroxidase complex method, with polyclonal rabbit anti-cod CYP1A. The results showed a markedly reduced expression of CYP1A in hepatocytes of starry flounder, which is consistent with the apparent resistance of this species to the development of hepatocellular neoplasia. This reduced expression of CYP1A in hepatocytes of contaminant-exposed fish was previously seen in oyster toadfish from the Elizabeth River, Virginia, and this species is also apparently resistant to hepatocellular neoplasia. 相似文献
250.
Zhang Yinglong J. Ye Fei Yu Haocheng Sun Weiling Moghimi Saeed Myers Edward Nunez Karinna Zhang Ruoyin Wang Harry Roland Aron Du Jiabi Liu Zhuo 《Ocean Dynamics》2020,70(5):621-640
Ocean Dynamics - Compound flooding is usually induced by the concurrence of coastal storm surge and heavy precipitation induced river flooding, with the former involving oceanic processes and the... 相似文献